Mixing of viscous immiscible liquids. Part 2: Overemulsification - interpretation and use

In mixing of immiscible fluids, the final steady state drop size distributi on, corresponding to a minimum mean drop size, is commonly approached in a monotonic way. There are, however, other scenarios. Overemulsification refe rs to cases where, (I) after reaching a minimum, the average size increases and then levels off to a final size, or (II) the average size oscillates. In case (I) the drop size distribution becomes bimodal after the average si ze goes through a minimum; gradually, the peak at smaller sizes moves towar ds the peak at larger sizes resulting in a narrow distribution, An explanat ion of this phenomenon is offered and ways to exploit it are suggested. (C) 2001 Elsevier Science Ltd. All rights reserved.