C. Cappelli et al., The Cotton-Mouton effect of gaseous N-2, CO, CO2, N2OOCS and CS2: a density functional approach to high-order mixed electric and magnetic properties, CHEM P LETT, 346(3-4), 2001, pp. 251-258
The static hypermagnetizability anisotropies of NT2, CO, CO2, N2O, OCS and
CS2 are computed using density functional theory (DFT). Also, the anisotrop
y of the electric dipole polarizability at a wavelength of 632.8 nm and tha
t of the magnetizability are obtained. We can thus compare the temperature
dependence of the Cotton-Mouton constant for all six molecules to the resul
ts of previous ab initio studies and to those of the experimental study by
Kling and Huttner [Chem. Phys. Lett. 90 (1984) 207]. The agreement is satis
factory. (C) 2001 Elsevier Science B.V. All rights reserved.