Controlling mechanisms of aluminium in soil solution - an evaluation of 180 podzolic forest soils

To monitor the level of soil acidification in the county of Varmland in the middle west of Sweden 180 podzolic forest soils were investigated. Soil so lutions from four horizons were obtained by centrifugation and the soil was sampled for a determination of the exchangeable pool by extraction. The co ncentrations of inorganic At and its fraction of the total Al in solution w ere greater in the south of the county (up to 50%). The factors influencing the total Al and free inorganic Al3+ in the soil solutions were evaluated. Saturation indices (ST) for five different mineral phases were calculated but none implied equilibrium conditions. The relationships between pAl(3+) and pH (in the pH range 4-6.2) gave slopes of about 1, which indicated that ion exchange/complexation reactions may be important for determining the A l3+ concentration in the B and C horizons. In the E horizon solutions compl exation with soluble organic acids seemed to be the major factor which infl uenced the Al3+ activity, The influence of organic matter on At solubility was supported by partial least square (PLS) regressions. (C) 2001 Elsevier Science Ltd. All rights reserved.