V. Brezova et al., SOLVENT EFFECT ON THE PHOTOCATALYTIC REDUCTION OF 4-NITROPHENOL IN TITANIUM-DIOXIDE SUSPENSIONS, Journal of photochemistry and photobiology. A, Chemistry, 107(1-3), 1997, pp. 233-237
The selective photocatalytic reduction of 1-nitrophenol to 4-aminophen
ol in titanium dioxide suspensions prepared in aliphatic alcohols (met
hanol, ethanol, 1-propanol, 2-propanol, 1-butanol, i-butanol) was inve
stigated. The photoreduction rate is significantly affected by the sol
vent parameters, such as viscosity, polarity, polarisability, and pola
rity/polarisability. (C) 1997 Elsevier Science S.A.