trans-[PtCl2(Am)(C2H4)] and [PtCl3(C2H4)](-)[AmH](+), containing binaphthyl secondary amines - Efficient chiral derivatizing agents for the enantiodiscrimination of chiral olefins by Pt-195 NMR spectroscopy

Authors
Uccello-Barretta, G Bernardini, R Balzano, F Venturelli, F Caporusso, AM Salvadori, P
Citation
G. Uccello-barretta et al., trans-[PtCl2(Am)(C2H4)] and [PtCl3(C2H4)](-)[AmH](+), containing binaphthyl secondary amines - Efficient chiral derivatizing agents for the enantiodiscrimination of chiral olefins by Pt-195 NMR spectroscopy, EUR J ORG C, (19), 2001, pp. 3651-3655
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
19
Year of publication
2001
Pages
3651 - 3655
Database
ISI
SICI code
1434-193X(200110):19<3651:TA[CB>2.0.ZU;2-G
Abstract
The complexes [PtCl3(C2H4)]-[AmH](+) and trans-[PtCl2(Am)(C2H4)], containin g the binaphthyl secondary amine (S)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-a] azepine, are efficient and versatile CDAs for the enantiodicrimination of s imple olefins by Pt-195 NMR analysis of their diastereoisomeric derivatives .