In order to characterise traditional balsamic vinegars from Modena some vol
atile compounds have been dosed. These substances, responsible for flavour,
were extracted after 3 h of stripping with nitrogen and adsorbed by activa
ted charcoal and tenax. The data collected were successively elaborated wit
h multivariate statistical techniques. While linear principal component ana
lysis (LPCA) could not permit an unequivocal differentiation, discriminant
method has given a complete discrimination among the various kinds of vineg
ars. (C) 2001 Elsevier Science Ltd. All rights reserved.