High-resolution powder neutron diffraction has been used to study the cryst
al structure of the (MgB2)-B-11 superconductor (T-c = 39.2 K) prepared at h
igh pressure in the temperature range 2 to 293 K. The experimental data pro
vide clear evidence of temperature-independent phase inhomogeneity, which w
as modelled by coexisting Mg1+deltaB2 phases. Precise structural informatio
n for temperatures near T-c also reveals extremely small volume and c-axis
discontinuities, consistent with the existence of a specific heat anomaly a
t T-c.