Radioisotope excited EDXRF analysis of sediment core samples from the southern part of the Black Sea

Citation
T. Akyuz et al., Radioisotope excited EDXRF analysis of sediment core samples from the southern part of the Black Sea, J RAD NUCL, 250(1), 2001, pp. 129-137
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
250
Issue
1
Year of publication
2001
Pages
129 - 137
Database
ISI
SICI code
0236-5731(200110)250:1<129:REEAOS>2.0.ZU;2-C
Abstract
In all 43 sediment samples were collected as gravity cores in depth from 70 to 150 cm from the 20 sampling sites of the continental slope of the south ern part of the Black Sea, during 1978. The samples were quantitatively ana lyzed by radioisotope excited energy dispersive X-ray fluorescence spectrom etry (EDXRF) using fundamental parameter technique (FTP). The investigated sediment samples were the organic rich-mud components of the core samples, which were known as rich in metals. The metal concentration ranges were as follows: Ca (3.1-12.9%), Ti (1000-2000 mug/g), V (40-150 mug/g), Cr (30-200 mug/g), Mn (200-1500 mug/g), Ni (25-100 mu /g), Cu (20-70 mug/g), Zn (20-5 0 mug/g), Br (15-670 mug/g), Rb (5-90 mug/g), Sr (80-700 mug/g), Y (10-20 m ug/g), Mo (10-111 mug/g), Zr (20-190 mug/g), Cd (<1-5 mug/g). Sb (<1-5 mug/ g), I (10-430 mug/g), Ba (100-1650 mug/g), La (5-18 mug/g), Ce (12-38 mug/g ) and Nd (6-17 mug/g). The sediment cores systematically collected in 1978 by Mineral Research and Exploration Institute of Turkey (MTA) are the oldes t available sediment samples from the Turkish coastline of the Black Sea. T herefore. the results may be used as references for monitoring possible fut ure metal pollution.