Tile characterization of a few Mexican clays with chemical treatment for po
ssible application as catalysers is shown. The natural clays are treated wi
th H2SO4, HF, F-3 CSO3H, ClSO3H, HClO4 and their behavior in reactions with
some alcohols was recorded. The analysis were made before and after using
the clays as catalysers. The clays were characterized by Mossbauer spectros
copy, X-ray diffraction, X-ray fluorescence analysis, and differential ther
mo analysis. The predominant mineral species are: montmorillonite, christob
alite and quartz. The main elements are: Si, Al, Fe, Ca, K etc. The Mossbau
er results show mainly a paramagnetic doublet of Fe3+. The clays behave sim
ilarly as described in the literature.