Structural effects of intercalation in [LiAl2(OH)(6)]Cl center dot xH(2)O (H-1, Li-7, Al-27 NMR)

Authors
Kozlova, SG Gabuda, SP Isupov, VP Chupakhina, LE
Citation
Sg. Kozlova et al., Structural effects of intercalation in [LiAl2(OH)(6)]Cl center dot xH(2)O (H-1, Li-7, Al-27 NMR), J STRUCT CH, 42(2), 2001, pp. 189-192
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
42
Issue
2
Year of publication
2001
Pages
189 - 192
Database
ISI
SICI code
0022-4766(200103/04)42:2<189:SEOII[>2.0.ZU;2-W
Abstract
H-1, Li-7, and Al-27 NMR was used to study [LiAl2(OH)(6)]Cl . xH(2)O system s (x = 0, 1.6, and 2.8). At larger x values, the amplitude of the libration al motion of the hydroxyl groups increases and the chloride ions are disord ered, while the localization of the lithium and aluminum ions does not chan ge.