METAL-HUMUS INTERACTION - NMR-STUDY OF MODEL COMPOUNDS

Authors
GRASSI M OLDANI E GATTI G
Citation
M. Grassi et al., METAL-HUMUS INTERACTION - NMR-STUDY OF MODEL COMPOUNDS, Annali di chimica, 87(5-6), 1997, pp. 353-357
Citations number
14
Categorie Soggetti
Chemistry Analytical","Environmental Sciences
Journal title
Annali di chimica → ACNP
ISSN journal
00034592
Volume
87
Issue
5-6
Year of publication
1997
Pages
353 - 357
Database
ISI
SICI code
0003-4592(1997)87:5-6<353:MI-NOM>2.0.ZU;2-S
Abstract
The NMR spectra were measured in solution, for a series of compounds m odelling the interaction of lead(II) with the humic substances of the soil. From the results it appears that the metal binding site is predo minantly the carboxylate group. The Pb-207 chemical shift is as a sens itive probe of the complexing ability of the various ligands and can b e used as an analitycal tool in the study of the interaction of this m etal with the soil organic matter.