Benzytriphenylphosphonium borohydride (BTPPB) as a selective reducing agent for reduction of imines, enamines, and reductive amination of aldehydes with primary and secondry amines in methanol
Ar. Hajipour et al., Benzytriphenylphosphonium borohydride (BTPPB) as a selective reducing agent for reduction of imines, enamines, and reductive amination of aldehydes with primary and secondry amines in methanol, PHOSPHOR SU, 170, 2001, pp. 197-203
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Benzyltriphenyltriphenylphosphonium borohydride (BTPPB) (1) generated as wh
ite solid from benzyltriphenylphosphonium chloride and sodium borohydride i
s found to be a selective and versatile reducing agent. The reagent in meth
anol is very useful for reduction of imines, enamines and reductive aminati
on of aldehydes.