Point defects, ferromagnetism, and transport in calcium hexaboride - art. no. 157204

The formation and local magnetic moment of a series of point defects in CaB 6 are computed using a supercell approach within the generalized gradient a pproximation to density functional theory. It is found that the substitutio n of Ca by La does not lead to the formation of a local moment, while a neu tral B-6 vacancy carries a moment of 2.4 Bohr magnetons. A plausible mechan ism for the ferromagnetic ordering of these moments is suggested. Since the same broken B-B bonds appear on the preferred (100) cleavage planes of the CaB6 structure, it is argued that internal surfaces in polycrystals as wel l as external surfaces in general will make a large contribution to the obs erved magnetization.