Perturbed angular correlation measurements in the HfAl2 C14-type Laves phas
e exhibit a very surprising temperature behavior of the ion-implanted In-11
1 probe atoms. Below 370 K the In-111 impurities are located at the unique
hafnium site. Above 400 K they occupy the two aluminum sites, however with
a clear preference of the 2(a) site. This process, which is fully reversibl
e when heating and cooling the sample, is attributed to atomic size effects
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