Organometallic derivatives of 2,6-di-tert-butylphenols as specific inhibitors of methyl oleate oxidation

Authors
Milaeva, ER Shpakovsky, DB Gracheva, YA Berberova, NT Egorov, MP
Citation
Er. Milaeva et al., Organometallic derivatives of 2,6-di-tert-butylphenols as specific inhibitors of methyl oleate oxidation, RUSS CHEM B, 50(6), 2001, pp. 1097-1100
Citations number
18
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
6
Year of publication
2001
Pages
1097 - 1100
Database
ISI
SICI code
1066-5285(200106)50:6<1097:ODO2AS>2.0.ZU;2-1
Abstract
2,6-Di-tert-butylphenols containing the Pt-SnCl3 and Pt-GeCl3 groups in the para position exert a dual effect on the oxidation of methyl oleate by mol ecular oxygen. Initially, these compounds act as antioxidants producing the corresponding phenoxyl radicals whose decomposition is accompanied by elim ination of SnCl2 and GeCl2, which are oxidation promoters.