CRYSTAL ENGINEERING - THE EFFECTS OF PI-PI INTERACTIONS IN COPPER(I) AND SILVER(I) COMPLEXES OF 2,7-DIAZAPYRENE

Authors
BLAKE AJ CHAMPNESS NR KHLOBYSTOV AN LEMENOVSKII DA LI WS SCHRODER M
Citation
Aj. Blake et al., CRYSTAL ENGINEERING - THE EFFECTS OF PI-PI INTERACTIONS IN COPPER(I) AND SILVER(I) COMPLEXES OF 2,7-DIAZAPYRENE, Chemical communications, (15), 1997, pp. 1339-1340
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1997
Pages
1339 - 1340
Database
ISI
SICI code
1359-7345(1997):15<1339:CE-TEO>2.0.ZU;2-Q
Abstract
The ligand 2,7-diazapyrene (L) is used to construct three- and two-dim ensional arrays with Cu-I and Ag-I ions: {[(CuL2)-L-I]PF6}(infinity) s hows an adamantoid network with three interpenetrating networks, while {[(AgL2)-L-I(MeCN)(2)]BF4}(infinity) forms linear chains of [AgL](inf inity) units linked by apparent pi-pi stacking and Ag ... Ag interacti ons between adjacent diazapyrene ligands to form two-dimensional sheet s.