Indium(III) chloride-catalyzed coupling reaction of acid chlorides and allylic tins

Authors
Inoue, K Shimizu, Y Shibata, I Baba, A
Citation
K. Inoue et al., Indium(III) chloride-catalyzed coupling reaction of acid chlorides and allylic tins, SYNLETT, (10), 2001, pp. 1659-1661
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
10
Year of publication
2001
Pages
1659 - 1661
Database
ISI
SICI code
0936-5214(200110):10<1659:ICCROA>2.0.ZU;2-9
Abstract
Allylic tributyltins and acid chlorides are effectively coupled to yield al lylic ketones in indium(III) chloride-catalyzed reactions. In the case of g amma -unsubstituted allylic tins, the assistance of a phosphine is essentia l to prevent further allylation of the produced ketones.