EFFICIENT COUPLING REACTIONS OF ALLYLAMINES WITH SOFT NUCLEOPHILES USING NICKEL-BASED CATALYSTS

Citation
H. Bricout et al., EFFICIENT COUPLING REACTIONS OF ALLYLAMINES WITH SOFT NUCLEOPHILES USING NICKEL-BASED CATALYSTS, Chemical communications, (15), 1997, pp. 1393-1394
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
15
Year of publication
1997
Pages
1393 - 1394
Database
ISI
SICI code
1359-7345(1997):15<1393:ECROAW>2.0.ZU;2-M
Abstract
Substitution reactions of N,N-diethylallylamine 1 with soft nucleophil es such as active methylene compounds 2a-c and piperidine 5 proceed mu ch more rapidly in the presence of Ni(dppb)(2) [dppb = 1,4-bis(dipheny lphosphino)butane] as catalyst than with comparable palladium systems.