Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol

Authors
Sato, I Omiya, D Tsukiyama, K Ogi, Y Soai, K
Citation
I. Sato et al., Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol, TETRAHEDR-A, 12(14), 2001, pp. 1965-1969
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
14
Year of publication
2001
Pages
1965 - 1969
Database
ISI
SICI code
0957-4166(20010814)12:14<1965:EOAAIT>2.0.ZU;2-H
Abstract
Kinetic analysis of the relationship between the reaction time and the yiel ds of the product in the enantioselective addition of diisopropylzinc to py rimidine-5-carbaldehyde using chiral pyrimidyl alkanol proves that the reac tion is autocatalytic. (C) 2001 Elsevier Science Ltd. All rights reserved.