PROBING PERISTATIC CHIRALITY OF ALKALINE CATIONS - NMR-STUDY OF ALKALINE BOROCRYPTATES

Authors
GRAF E GRAFF R HOSSEINI MW HUGUENARD C TAULELLE F
Citation
E. Graf et al., PROBING PERISTATIC CHIRALITY OF ALKALINE CATIONS - NMR-STUDY OF ALKALINE BOROCRYPTATES, Chemical communications, (15), 1997, pp. 1459-1460
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1997
Pages
1459 - 1460
Database
ISI
SICI code
1359-7345(1997):15<1459:PPCOAC>2.0.ZU;2-F
Abstract
Enantiomeric differentiation of chiral borocryptates using NMR spectro scopy in a chiral liquid crystalline medium is achieved using differen t NMR probes localised both on the receptor and on the substrate; the observed chirality at the substrate is described as being induced by t he spiroborate junction and mediated by the peristatic chirality of th e cavity.