Applying the pulsed laser deposition (PLD) technique, diamond-like carbon (
DLC) films were prepared, Arc conditioning of these PLD thin films yields i
ntense cold electron field emission (FE), with the turn-on field being as l
ow as 1.4 V/mum. Tentative UV light irradiation resulted in an intense simu
ltaneous FE and photoemission (FEPES) at a 10% level, indicating a rather e
fficient field enhancement. The modified surface areas were characterized u
sing techniques with outstanding surface sensitivity such as X-ray photoele
ctron spectroscopy (XPS) or a high lateral resolution such as Micro-Raman a
nd scanning tunneling field electron emission microscopy (FEEM) and spectro
scopy (FEES). It was above all the application of the latter method which r
evealed a prevailing intrinsic character of this particular FE effect. The
lateral distribution of the activated electron-emitting dot matrix is rathe
r non-uniform which still impedes display applications, However, replacemen
t of radioactive foils in gas-analytical devices can be hopefully envisaged
. (C) 2001 Elsevier Science B.V. All rights reserved.