The objective of this research was to investigate the feasibility of activa
ting vapor-grown carbon fibers (VGCFs) with supercritical fluids (SCFs). VG
CFs with a mean diameter of 150 nm and a length of a few micrometres were t
reated using water or carbon dioxide under supercritical conditions for 10
min. Hydrochloric acid and nitric acid were utilized for the oxidation of t
he VGCFs prior to the treatment of the SCFs. The nitrogen adsorption result
s at 77 K showed that the BET surface area of the treated VGCFs can be incr
eased from 9 m(2)/g to about 35 m(2)/g. The adsorption of benzene vapor on
the VGCFs revealed that the adsorption capacity of benzene was enhanced aft
er the activation treatments. However, in comparison with commercial activa
ted carbon fibers (ACF), the adsorption amount of benzene is still relative
ly low. Based on the CHN elemental analysis and X-ray photoelectron spectro
scopy (XPS), it was found that oxygen compounds were contained on/in the VG
CFs after the treatment by oxidation and by SCFs. (C) 2001 Elsevier Science
Ltd. All rights reserved.