Mesostructured and mesoporous materials are emerging as a new class of opti
cal materials. For mesostructured materials (inorganic/surfactant composite
s), prepared using a one-step synthesis procedure where the inorganic/surfa
ctant/optically active species coassemble, the unique architecture provided
by the surfactant-inorganic phase separation allows for higher concentrati
ons compared to traditional sol-gel glasses and protective packaging of uni
form three-dimensional arrays of optical species. The corresponding regular
ly arranged pores found in mesoporous materials (inorganic only) provide a
high surface area to better disperse optically active components and allow
for rapid diffusion for optical sensor applications. In this review, we dis
cuss recent research results on the techniques used to produce optically fu
nctionalized mesostructured and mesoporous materials and the characterizati
on of the final composites.