A number of polyimides have gained considerable importance as high-performa
nce polymers during the last 2 decades primarily because of their excellent
thermal stability and toughness. Some applications, however, require prope
rty enhancements and the desired improvements can often be obtained through
incorporation of ceramic-like particles such as silica. Such hybrid inorga
nic-organic composites are frequently obtained using the in situ generation
of the dispersed inorganic phase by the sol-gel technique. A number of stu
dies have now been carried out on the preparation and characterization of s
uch hybrid polyimide composites, and the purpose of this review is to give
a brief account of the strategies used for this purpose and to describe som
e of the properties of the resulting composites.