L. Wang et Mg. Kanatzidis, Laminated TaS2/polymer nanocomposites through encapsulative precipitation of exfoliated layers, CHEM MATER, 13(10), 2001, pp. 3717-3727
Several TaS2/polymer nanocomposites prepared through the encapsulative prec
ipitation method are described. Namely, the encapsulation of poly(ethylene
oxide) (PEO), polyethylene imine (PEI), and poly(vinylpyrrolidinone) (PVP)
into TaS2 was examined in detail, and the nanocomposites were characterized
by a wide variety of techniques. The nanocomposites disperse in water and
are easily cast into free-standing films. The flexible metallic TaS2/ polym
er nanocomposite films display bulk superconductivity. In addition, in this
work the exfoliation properties of LixTaS2 were systematically explored, a
nd it was found that material prepared from controlled lithiation with 0.2
equiv of LiBH4 exfoliates well in water and has high affinity for various p
olymers. The likely conformation of PEO molecules sandwiched between the Ta
S2 slabs was explored with analysis of the X-ray diffraction patterns of a
highly oriented Li-x(PEO)(y),TaS2 nanocomposite films. The one-dimensional
electron density maps, obtained for Li-x(PEOy,TaS2, can be explained with t
wo sheets of PEO chains (bilayer) that adopt a conformation similar to that
found in a type II PEO-HgCl2 complex. The chains are arranged with the -CH
2- groups facing the TaS2 layers and the -O- atoms toward the center of the
gallery, where the Li+ ions seem to be located. Solid state Li-7 NMR measu
rements indicate that Li-x(PEO),yTaS2 provides a more facile hopping enviro
nment for Li ions than pristine LixTaS2.