Yb. Wang et al., Observation of Rydberg series in sodium vapour by two-photon resonant nondegenerate four-wave mixing, CHIN PHYS L, 18(9), 2001, pp. 1202-1204
We apply two-photon resonant nondegenerate four-wave mixing with a resonant
intermediate state for the observation of Rydberg states in sodium vapour.
The broadening and shift of the sodium 3S-11D transition perturbed by argo
n are investigated. This technique can achieve Doppler-free resolution of n
arrow spectral structures of Rydberg levels if lasers with narrow bandwidth
s are employed.