Tuning anisotropy by impurities: magnetocaloric experiments on CsNi0.9Fe0.1Cl3

Citation
J. Wolf et al., Tuning anisotropy by impurities: magnetocaloric experiments on CsNi0.9Fe0.1Cl3, EUR PHY J B, 22(4), 2001, pp. 461-471
Citations number
28
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL B
ISSN journal
14346028 → ACNP
Volume
22
Issue
4
Year of publication
2001
Pages
461 - 471
Database
ISI
SICI code
1434-6028(200108)22:4<461:TABIME>2.0.ZU;2-C
Abstract
The magnetic phase diagram of the Fe2+ doped hexagonal ABX(3) compound CsNi 0.9Fe0.1Cl3 is investigated by heat capacity and magnetocaloric experiments . In spite of the high doping concentration, some phase boundaries appear s urprisingly well-defined, while others are broadened significantly. The dis cussion of this behaviour clarifies the potentials and limitations of dopin g as a means to manipulate the effective anisotropy in quasi one-dimensiona l ABX(3) compounds.