Synthesis of spirocyclic ethers by radical cyclization of epoxides using atransition-metal radical source

Authors
Rana, KK Guin, C Roy, SC
Citation
Kk. Rana et al., Synthesis of spirocyclic ethers by radical cyclization of epoxides using atransition-metal radical source, I J CHEM B, 40(10), 2001, pp. 925-929
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
40
Issue
10
Year of publication
2001
Pages
925 - 929
Database
ISI
SICI code
0376-4699(200110)40:10<925:SOSEBR>2.0.ZU;2-B
Abstract
A series of spirocyclic ethers, possible versatile intermediates towards na turally occurring compounds, have been synthesized by radical cyclization o f epoxides. The carbon-centered radical from an epoxide is generated by usi ng a Ti(III) radical initiator.