Silver(I) coordination polymers of cyclic sulfur ligand, 2,2 ',3,3 '-tetrahydro-4,4 '-dithia-1,1 '-binaphthylidene

Citation
M. Wen et al., Silver(I) coordination polymers of cyclic sulfur ligand, 2,2 ',3,3 '-tetrahydro-4,4 '-dithia-1,1 '-binaphthylidene, INORG CHIM, 322(1-2), 2001, pp. 133-137
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
322
Issue
1-2
Year of publication
2001
Pages
133 - 137
Database
ISI
SICI code
0020-1693(20011008)322:1-2<133:SCPOCS>2.0.ZU;2-L
Abstract
The silver(I) complexes of 2,2',3,3'-tetrahydro-4,4'-dithia-1,1'-binaphthyl idene (ttp) having a nine-member S-Ag-S chelating ring, [Ag(ttp)(ClO4)](n) (1) and [Ag-2(ttp)(2)(CF3SO3)(2)](n) (2), have been synthesized and charact erized by single-crystal X-ray diffraction. The ttp is found to offer a pot ential coordination site for complexation, which can be utilized to generat e an interesting array of silver(l) complexes with a one-dimensional chain and a chiral chain. (C) 2001 Elsevier Science B.V. All rights reserved.