J. Galvan-miyoshi et al., Localized oscillations and Fraunhofer diffraction in crystalline phases ofa monolayer, J CHEM PHYS, 115(17), 2001, pp. 8178-8184
Localized oscillations present in the crystalline phases of the heneicosano
ic acid Langmuir monolayer were studied in detail. They appear like blinkin
g interference rings, when observed with Brewster angle microscopy. Monolay
ers with localized oscillations were transferred on mica to be characterize
d by atomic force microscopy. We found granules produced by the expulsion o
f matter from the monolayer. However, these granules are too short to produ
ce Newton's rings; the common belief of the origin of the interference ring
s in the field of Langmuir monolayers. The analysis of the light intensity
distribution and the sizes of the rings are consistent with Airy patterns p
roduced by Fraunhofer diffraction due to the reflected light from the multi
layer granules. The origin of the blinking of these patterns is still uncle
ar. (C) 2001 American Institute of Physics.