Application of the method of continued fractions to multichannel studies on electron-impact excitation of the B-1 Sigma(+)(u), (CIIu)-I-1 and E(F)(1)Sigma(+)(g) states in H-2
Am. Machado et al., Application of the method of continued fractions to multichannel studies on electron-impact excitation of the B-1 Sigma(+)(u), (CIIu)-I-1 and E(F)(1)Sigma(+)(g) states in H-2, J MOL ST-TH, 574, 2001, pp. 133-140
In the present work, the method of continued fractions at a five-channel cl
ose-coupling level of approximation is applied to study the low-energy elec
tron-impact excitation in linear molecules. Particularly, cross sections fo
r the X(1)Sigma (+)(g)-->B(1)Sigma (+)(u), X(1)Sigma (+)(g)-->E(F)(1)Sigma
(+)(g), and X(1)Sigma (+)(g)-->(CIIu)-I-1 transitions in H-2 in the (15-40)
eV energy range are reported. No orthogonality constraint between the boun
d and continuum orbitals is imposed in the present study and the one-electr
on exchange terms are explicitly considered. Comparison between our calcula
ted cross sections with the available experimental data and other theoretic
al results is made. (C) 2001 Elsevier Science B.V. All rights reserved.