Functionalized iminium salt systems for catalytic asymmetric epoxidation

Authors
Page, PCB Rassias, GA Barros, D Ardakani, A Buckley, B Bethell, D Smith, TAD Slawin, AMZ
Citation
Pcb. Page et al., Functionalized iminium salt systems for catalytic asymmetric epoxidation, J ORG CHEM, 66(21), 2001, pp. 6926-6931
Citations number
99
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
66
Issue
21
Year of publication
2001
Pages
6926 - 6931
Database
ISI
SICI code
0022-3263(20011019)66:21<6926:FISSFC>2.0.ZU;2-M
Abstract
A range of dihydroisoquinolinium salts containing alcohol, ether, and aceta l functionalities in the nitrogen substituent has been prepared and tested as asymmetric epoxidation catalysts, providing ee's of up to ca. 60%.