We have studied the effect of Cu contamination in oxynitride gate dielectri
cs. Compared to thermal SiO2 with a physical thickness of 3-5 nm, the oxyni
tride shows a much improved Cu contamination resistance. Furthermore, the C
u contamination resistance increases with increasing nitrogen content. The
mechanism of improved gate dielectric resistance to Cu is due to the strong
diffusion barrier properties of oxynitride as observed by secondary ion ma
ss spectroscopy. (C) 2001 The Electrochemical Society.