Water molecules retained in native cellulose gels obtained from Acetobacter
xylinum (AX) were displaced by poly(ethylene glycol)s (PEG) of different m
olecular weight. The so obtained native cellulose/PEG material, characteriz
ed in film form by differential scanning calorimetry, dynamic mechanical th
ermal analysis and wide angle X-ray scattering, revealed that strong intera
ctions occur between PEG and cellulose and that the polymer mixture is in t
he rubbery state at ambient temperature. Moreover, it could be dyed in supe
rcritical carbon dioxide by disperse dyes, thus exhibiting typically lipoph
ilic properties and suitability to be employed as a biocompatible support f
or lipophilic active species.