The nuclear and magnetic structures of the double provskite compound Ca2MnW
O6 have been determined by neutron powder diffraction. Rietveld refinement
shows that the compound adopts a monoclinic crystal structure with P2(1)/n
symmetry. Magnetic refinement at 10 K shows that the magnetic structure is
based on a unit cell related to that of the nuclear structure by a propagat
ion vector (0 1/2 1/2), which is not very common in the case of double pero
vskites. The crystal contains alternating MnO6 and WO6 octahedra, considera
bly tilted due to the relative small size of the cation that occupy the A-s
ublattice of the perovskite. The manganese magnetic moments are coupled ant
iferromagnetically along the unit cell axes with the magnetic moment equal
to 3.49(2) mu (B) (M-x = 1.08(13) mu (B), M-y = 0.94(7) mu (B), M-z = 3.20(
4) mu (B)). Antiferromagnetic behavior was confirmed by magnetization measu
rements, and the antiferromagnetic to paramagnetic transition was found at
16 +/- 0.1 K. (C) 2001 Elsevier Science Ltd. All rights reserved.