Incorporation of three phenylacetylene molecules into an RhMo2S4 trinuclear sulfido cluster core, forming bridging metallathiacyclobutene and dithiolene moieties

Authors
Ikada, T Mizobe, Y Hidai, M
Citation
T. Ikada et al., Incorporation of three phenylacetylene molecules into an RhMo2S4 trinuclear sulfido cluster core, forming bridging metallathiacyclobutene and dithiolene moieties, ORGANOMETAL, 20(21), 2001, pp. 4441-4444
Citations number
57
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
21
Year of publication
2001
Pages
4441 - 4444
Database
ISI
SICI code
0276-7333(20011015)20:21<4441:IOTPMI>2.0.ZU;2-Y
Abstract
The trinuclear sulfido cluster [{Rh(PPh3)(2)}-(mu (3)-S)(mu (2)-S)(3){Mo(S2 CNEt2)}(2)(mu (2)-Cl)] (2a) reacted readily with three PhC equivalent to CH molecules to afford [{Rh(SCPh=CH)Cl(PPh3)}{Mo(SCPh=CH)(S2CNEt2)}{Mo(S2C2HP h)(S2CNEt2)}], the structure of which, as well as that of the PMePh2 analog ue of 2a, have been determined by X-ray analyses.