Mechanism and efficiency of the inhibiting action of 1,3-di-(4-phenylaminophenoxy)-2-propanol and 2,6-di-tert-butyl-4-methylphenol in the oxidation of methyl linoleate

Citation
Av. Pis'Menskii et al., Mechanism and efficiency of the inhibiting action of 1,3-di-(4-phenylaminophenoxy)-2-propanol and 2,6-di-tert-butyl-4-methylphenol in the oxidation of methyl linoleate, PETR CHEM, 41(5), 2001, pp. 346-351
Citations number
10
Categorie Soggetti
Chemical Engineering
Journal title
PETROLEUM CHEMISTRY
ISSN journal
09655441 → ACNP
Volume
41
Issue
5
Year of publication
2001
Pages
346 - 351
Database
ISI
SICI code
0965-5441(200109/10)41:5<346:MAEOTI>2.0.ZU;2-V
Abstract
The mechanism of the inhibiting action of the aromatic amine 1,3-di-(4-phen ylaminophenoxy)-2-propanol and the sterically hindered phenol 2,6-di-tert-b utyl-4-methylphenol (ionol) in oxidizing methyl linoleate was studied. The key reactions in the mechanism of inhibition by the antioxidants were ident ified, and the corresponding kinetic parameters were estimated. The mechani sms of the action of the antioxidants were compared, and the reasons for th e main differences in their efficiency were established.