This paper reports a study of the relationship between purpose-designed, it
erative multi-stage thermomechanical treatments, grain boundary crystallogr
aphy and subsequent ductility in alpha-brass. Grain boundary crystallograph
ies were analysed not only in terms of proportions of coincidence site latt
ice (CSL) types but also, crucially, as proximity to the exact CSL referenc
e structure. The only CSLs that were present in significant proportions wer
e Sigma 3s, and those Sigma 3s with intermediate proximity to the exact CSL
misorientation were identified as high mobility boundaries. Variation in m
obility at a Sigma3 as a function of deviation from the exact CSL configura
tion is discussed in detail. For two selected specimens modifying the strai
n-annealing regimes resulted in ductilities of 53% and 74% respectively. Th
e enhanced ductility in one specimen is probably the result of a combinatio
n of strain-induced grain growth and increased proportions of Sigma 3s with
intermediate proximity to the exact CSL misorientation.