G. Majkic et al., A transmission electron microscopy study of polycrystalline SrCo0.8Fe0.2O3-delta creep in the diffusion-to-power law transition regime, PHIL MAG A, 81(11), 2001, pp. 2675-2688
This study is aimed at elucidating the nature of power-law creep, threshold
stress and stress-induced diffusion in SrCo0.8Fe0.2O3-delta samples subjec
ted to creep. A SrCo0.8Fe0.2O3-delta sample deformed in the transition from
a diffusion to a power-law creep regime (900 degreesC, 50 MPa and 15% stra
in) as well as an as-sintered sample were analysed by transmission electron
microscopy and energy-dispersive X-ray spectroscopy. The dislocation struc
ture has been found to be highly non-uniform with areas of high dislocation
density confined only within a set of well-separated grains. The dislocati
on structure and distribution indicate that this compound deforms by cooper
ative grain-boundary sliding in the transition regime. In the grains that d
o deform by dislocation movement, deformation is achieved by slip through t
he screw [1 (1) over bar0][110] system. A planar map of the composition dis
tribution of constituent cations revealed large fluctuations in cation comp
osition over distances of the order of 100-200 nm, as well as a complementa
ry distribution trend of cobalt and iron. This behaviour is found to be due
to sequential stress-induced diffusion of cations, which is in accordance
with the temperature dependence of the apparent activation energy. The conc
entration profiles perpendicular to grain boundaries clearly reveal no pref
erential segregation of cations at neither random nor coincident-site latti
ce grain boundaries, which excludes dopant segregation as the mechanism res
ponsible for the threshold stress-like behaviour at low stresses.