Citation
L. Uehlin et T. Wirth, Mixed acetals as new precursors for selenium electrophiles, PHOSPHOR SU, 171, 2001, pp. 443-448
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507
→ ACNP
Volume
171
Year of publication
2001
Pages
443 - 448
Database
ISI
SICI code
1042-6507(2001)171:<443:MAANPF>2.0.ZU;2-6
Abstract
A wide range of precursors for selenium electrophiles is already known, but
the requirements for the development of polymer-bound selenium reagents ar
e different. Herein we report mixed acetals as new precursor molecules for
the synthesis of selenium electophiles under very mild reaction conditions.
The use of (MeOCH2Se)(2) allows a very fast access to these mixed acetals.
Chiral precursor molecules can be synthesized as well and employed in effi
cient stereoselective selenenylation reactions.