InGaAs/InP strained-layer modulation-doped quantum wells were studied by ph
otoluminescence. The combination of the built-in strain and the quantum con
finement in this system leads to a strong valence band mixing yielding dire
ct and indirect band gap structures. We demonstrate that the optical emissi
on line shape is strongly dependent on the valence band dispersion and it i
s a good method to distinguish between direct and indirect structures. The
application of an external biaxial tensile strain to the samples provides a
n additional evidence of direct-to-indirect band gap transition in strained
heterostructures.