Crossover from first-order to critical wetting: Short-range tricritical wetting - art. no. 176103

We study wetting in liquid mixtures of methanol and the n-alkanes. Mixing a lkanes of different chain lengths, we can examine the crossover between cri tical (continuous) and first-order (discontinuous) wetting transitions. Mea surements of the film thickness and surface specific heat exponent indicate that for carbon number n between 11 (undecane) and 9 (nonane), there is a crossover from first-order to critical wetting with a tricritical wetting p oint between an effective alkane carbon number of 9.6 and 10. The observed variation of the specific heat exponent in the tricritical region agrees fa irly well with the predictions of a simple mean-field model with only short -range interactions.