Aa. Kamnev et E. Kuzmann, MOSSBAUER SPECTROSCOPIC EVIDENCE FOR THE REDUCTION OF IRON(III) BY ANTHRANILIC ACID IN AQUEOUS-SOLUTION, Polyhedron, 16(19), 1997, pp. 3353-3356
The data of Mossbauer spectroscopic measurements in rapidly frozen aci
dified Fe-57(III) nitrate solutions containing anthranilic acid are pr
esented and discussed. The results obtained provide direct evidence th
at, along with the formation of an iron(III) anthranilate complex, gra
dual reduction of iron(III) by anthranilic acid occurs with the format
ion of iron(II) species even in acidic nitrate media. (C) 1997 Elsevie
r Science Ltd.