SYNTHESIS AND DNA-BINDING STUDIES OF CO-III MIXED-LIGAND COMPLEX CONTAINING DIPYRIDO[3,2-A-2',3'-C]PHENAZINE AND PHEN

Authors
JIN L YANG P
Citation
L. Jin et P. Yang, SYNTHESIS AND DNA-BINDING STUDIES OF CO-III MIXED-LIGAND COMPLEX CONTAINING DIPYRIDO[3,2-A-2',3'-C]PHENAZINE AND PHEN, Polyhedron, 16(19), 1997, pp. 3395-3398
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
19
Year of publication
1997
Pages
3395 - 3398
Database
ISI
SICI code
0277-5387(1997)16:19<3395:SADSOC>2.0.ZU;2-X
Abstract
The complexion [Co(phen)(2)dppz](3+) (where phen is o-phenanthroline, and dppz is dipyrido[3,2-a: 2',3'-c] phenazine) has been synthesized. This complex (as perchlorate salt) was characterized by elemental anal ysis, molar conductivity and IR spectra. The interact:ion of the compl ex with calf thymus DNA has been studied using absorption spectra and fluorescence spectra. The complex is also shown to be a more efficient photosensitiser for single strand breaks in plasmid DNA. (C) 1997 Els evier Science Ltd.