SYNTHESIS AND CHARACTERIZATION OF METALLIC COMPLEXES OF 3-(2-FURYL) 2-PROPENAL SEMICARBAZONE WITH D-ELEMENT DIHALIDES

Authors
IBRAHIM G KHAN MA RICHOMME P BENALIBAITICH O BOUET G
Citation
G. Ibrahim et al., SYNTHESIS AND CHARACTERIZATION OF METALLIC COMPLEXES OF 3-(2-FURYL) 2-PROPENAL SEMICARBAZONE WITH D-ELEMENT DIHALIDES, Polyhedron, 16(19), 1997, pp. 3455-3461
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
19
Year of publication
1997
Pages
3455 - 3461
Database
ISI
SICI code
0277-5387(1997)16:19<3455:SACOMC>2.0.ZU;2-M
Abstract
3-(2-Furyl) 2-propenal semicarbazone (FASC) and Co-II, Ni-II, Cu-II, Z n-II and Cd-II chlorides or bromides gave the complexes: [M(FASC)(2)X- 2], [M(FASC)(2)]X-2, or [M(FASC)X-2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic sp ectra; in addition, the NMR data are used in the case of Zn-II and Cd- II species. The main cell parameters are given using X-ray diffraction powder diagrams. (C) 1997 Elsevier Science Ltd.