C. Dowling et al., STRUCTURAL CHARACTERIZATION OF BIS(PYRAZOLYL)HYDROBORATO THALLIUM COMPLEXES - MONOMERIC 2-COORDINATE THALLIUM DERIVATIVES SUPPLEMENTED BY [TL-H-B] INTERACTIONS, Polyhedron, 16(19), 1997, pp. 3469-3473
The syntheses and structural characterization of a series of mononucle
ar bis(pyrazolyl)hydroborato thallium complexes Tl[Bp(But,R)] (R = Me,
Pr-i, Bu-t) are described. In each case, the two-coordinate Tl(I) cen
ters of Tl[Bp(But,R)] are supplemented by secondary [Tl ... H-B] inter
actions. (C) 1997 Elsevier Science Ltd.