STRUCTURAL CHARACTERIZATION OF BIS(PYRAZOLYL)HYDROBORATO THALLIUM COMPLEXES - MONOMERIC 2-COORDINATE THALLIUM DERIVATIVES SUPPLEMENTED BY [TL-H-B] INTERACTIONS

Citation
C. Dowling et al., STRUCTURAL CHARACTERIZATION OF BIS(PYRAZOLYL)HYDROBORATO THALLIUM COMPLEXES - MONOMERIC 2-COORDINATE THALLIUM DERIVATIVES SUPPLEMENTED BY [TL-H-B] INTERACTIONS, Polyhedron, 16(19), 1997, pp. 3469-3473
Citations number
62
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
16
Issue
19
Year of publication
1997
Pages
3469 - 3473
Database
ISI
SICI code
0277-5387(1997)16:19<3469:SCOBTC>2.0.ZU;2-T
Abstract
The syntheses and structural characterization of a series of mononucle ar bis(pyrazolyl)hydroborato thallium complexes Tl[Bp(But,R)] (R = Me, Pr-i, Bu-t) are described. In each case, the two-coordinate Tl(I) cen ters of Tl[Bp(But,R)] are supplemented by secondary [Tl ... H-B] inter actions. (C) 1997 Elsevier Science Ltd.