A novel preparation route of TWC, which is combined with the synthesis of n
anosized (Ce-Zr-M)O-2 (M = La, Pr) solid solution by modified sol-gel metho
d, is introduced. The TWC precursor shows high thermal stability and posses
ses high OSC. High thermally stable TWCs with this kind of precursors are a
lso exhibited. The main reason is discussed.