J. Lachenmaier et al., Emission reduction of regenerative fuel powered co-generation plants with SCR- and oxidation-catalysts, TOP CATAL, 16(1-4), 2001, pp. 437-442
Since the beginning of combustion engine development in this recent century
various different fuels have been successfully tested. Diesel engines have
been adapted to fuels made from mineral oils because of the rising importa
nce and the cheapness in comparison to other fuels. On the other hand, it i
s possible to burn regenerative fuels in engines and achieve some significa
nt advantages in comparison to fossil diesel fuel. This is, for example, a
closed carbon dioxide (CO2) cycle which causes no green house effect. It is
possible to extract oil from various seeds like rapeseed. It is also possi
ble to burn used oil from the food processing industry or waste grease and
oil from food recycling companies. The great advantages: (1) food recycling
oils can produce energy instead of use as animal food, and (2) as nobody k
nows exactly the consistency of the collected oils, poisonous pollution is
possible. These regenerative fuels can be burned without any further proces
sing in special adapted diesel engines, for example an Elsbett engine, or i
n precombustion engines with large swept volumes. Most researchers focused
on operating diesel engines with regenerative fuels and reducing the emissi
ons caring only about regulated exhaust components. In comparison to these
studies it is necessary to learn more about the emissions beyond the exhaus
t regulations. Additionally emission reduction is possible by using an SCR-
catalyst (selective catalytic reduction) to reduce the NO2 combined with an
oxidation-catalyst which reduces any kind of oxidisable emissions. The TU
Munchen, Lehrstuhl fur Energie- und Umwelttechnik der Lebensmittelindustrie
, operates a small co-generation plant with the ability of analysing the st
andard emission components (CO, NO2, HC, particles, CO2, O-2) and unregulat
ed components (SO2, NH3, polycyclic aromatic hydrocarbons (PAH), aldehyde,
ketone). The emissions show some significant differences in comparison to f
ossil diesel fuel which is caused by the diversity of each fuel. Results of
an investigation on four different fuels (wastefat methyl ester (WME), rap
eseed methyl ester (RME), rapeseed oil and diesel fuel) burned in a small c
o-generation plant with a SCR- and oxidation-catalyst will be presented. A
comparison to the emissions before and after the catalysts will be shown ad
ditionally to the results of the different reduction potential of diesel fu
el, methyl ester or untreated oils. The combination of regenerative fuel an
d catalyst shows good potential for reducing the emissions. Furthermore the
use of regenerative fuels is a sustainable production of energy with an ov
erall efficiency of almost 90%. Regenerative fuels based on vegetable oils
and waste fat are a valuable form of energy and have some significant advan
tages in comparison to diesel fuel, like an almost closed carbon dioxide cy
cle, rapid biological decomposition and lower CO, HC and particle emissions
. Regenerative fuels should also meet minimum standards discussed in the pa
per to avoid the risk of engine damage and to reduce emissions.