Activated carbons prepared from phosphoric acid activation of grain sorghum

The production of activated carbons from grain sorghum with phosphoric acid activation has been studied by means of two processes, i.e., one-stage and two-stage. The former comprises simultaneous carbonization and activation after impregnation; the latter, the carbonization of the precursor at 300 d egreesC for 15 min, followed by the activation of the resultant char after impregnation with phosphoric acid. The preparation conditions, e.g., activa tion duration, phosphoric acid concentration, and activation temperature, h ave been varied to determine the optimal processing conditions. The optimal activation conditions for the highest surface areas have been determined t o be 600 and 500 degreesC with a phosphoric acid concentration of 35% for t he one-stage and two-stage processes, respectively. The two-stage process h as been found to greatly enhance the porosity development, especially the m icroporosity. (C) 2001 Elsevier Science Ltd. All rights reserved.