Authors
Citation
B. Schwarze et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [(CL3S I)(2)N](2)TICL2 - A FULLY CHLORINATED N-SILYL TITANIUM AMIDE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(7), 1997, pp. 819-822
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
52
Issue
7
Year of publication
1997
Pages
819 - 822
Database
ISI
SICI code
0932-0776(1997)52:7<819:SACO[I>2.0.ZU;2-U
Abstract
The chlorinated titanium amides [(Cl3Si)(2)N](2)TiCl2 (1) and (Cl3Si)(
2)NTiCl3 have been synthesized selectively from hexachlorodisilazane l
ithium and TiCl4. The crystal structure of 1 was determined by single
crystal X-ray methods at room temperature (P2(1)2(1)2(1), a = 1232.4(2
), b = 1265.5(2), c = 1469.1(2) pm, Z = 4). The central titanium atom
of 1 is bound to two nitrogen atoms and two Cl atoms and is weakly coo
rdinated further by two Cl atoms of the trichlorosilyl groups.